Aqueous Solutions of Simple Electrolytes.pdf

Aqueous Solutions of Simple Electrolytes PDF

Felix Franks

The chapters making up this volume had originally been planned to form part of a single volume covering solid hydrates and aqueous solutions of simple molecules and ions. However, during the preparation of the manu­ scripts it became apparent that such a volume would turn out to be very unwieldy and I reluctantly decided to recommend the publication of sepa­ rate volumes. The most sensible way of dividing the subject matter seemed to lie in the separation of simple ionic solutions. The emphasis in the present volume is placed on ion-solvent effects, since a number of excellent texts cover the more general aspects of electrolyte solutions, based on the classical theories of Debye, Huckel, On sager, and Fuoss. It is interesting to speculate as to when a theory becomes classical. Perhaps this occurs when it has become well known, well liked, and much adapted. The above-mentioned theories of ionic equilibria and transport certainly fulfill these criteria. There comes a time when the refinements and modifications can no longer be related to physical significance and can no longer hide the fact that certain fundamental assumptions made in the development of the theory are untenable, especially in the light of information obtained from the application of sophisticated molecular and thermodynamic techniques.

10.01.2012 · We report orientational anchoring transitions at aqueous interfaces of a water-immiscible, thermotropic liquid crystal (LC; nematic phase of 4′-pentyl-4-cyanobiphenyl) that are induced by changes in pH of the aqueous solution and the addition of simple electrolytes (NaCl) to the aqueous phase.

1468429574 ISBN
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Aqueous Solutions of Simple Electrolytes.pdf


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In this paper, we focused on the correlation of the thermodynamic properties of aqueous solutions across a temperature range from (273.15 to 523.15) K by a simple two-parameter model. This model is based on the modified three-characteristic-parameter correlation (TCPC) model. The two parameters, b, distance of closest approach, and S, solvation parameter, represent the interactions between Aqueous Solutions of Simple …

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Electrolyte - Wikipedia An electrolyte is a substance that produces an electrically conducting solution when dissolved in a polar solvent, such as water.The dissolved electrolyte separates into cations and anions, which disperse uniformly through the solvent.Electrically, such a solution is neutral. If an electric potential is applied to such a solution, the cations of the solution are drawn to the electrode that has

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4 May 2011 ... Solvation of Electrolytes and Nonelectrolytes in Aqueous Solutions ... the molar volume of solution in hydration shells than a simple change of ...

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